I caught my first episode of ROH on HDNet the other day...and man, I was impressed. The Bravado brothers were incredibly fun to watch. Their line about facing the Worlds Greatest Tag Team (from seven years ago) was brilliant.
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The title isn't Smackdown! exclusive. Nor, really, is Brock. He's just being bribed (storyline-wise) to not appear on Raw. According to the way they set it up at the start, the champ CAN appear on both shows. Nobody ever (to my recollection)